The following is a list of peer-reviewed papers from the Gray Group, in reverse-chronological order from date of publication.
Heckler, J. E.; Anderson, B. L.; Gray, T. G. “A tri-gold triazolide with long-lived luminescence” J. Organomet. Chem. 2016, 818, 68–81. (DOI: 10.1016/j.jorganchem.2016.05.020)
Wyss, C. M.; Bitting, J.; Basca, J.; Gray, T. G.; Sadighi, J. P. “Bonding and Reactivity of a Dicopper(I) μ-Boryl Cation” Organometallics 2016, 35, 71-74. (DOI: 10.1021/acs.organomet.5b00961)
Ayoub, N. A.; Browne, A. R.; Anderson, B. L.; Gray, T. G. “Cyclometalated gold(III) trioxadiborrin complexes: studies of the bonding and excited states” Dalton Trans. 2016, 45, 3820-3830. (DOI: 10.1039/C5DT04732C)
Browne, A. R.; Deligonul, N.; Anderson, B. L.; Zeller, M.; Hunter, A. D.; Gray, T. G. “Cyclometalated (boroxinato)gold(III) complexes from arrested transmetalation” Chem. Commun. 2015, 51, 15800-15803. (DOI: 10.1039/C5CC05200A)
Choi, J.-S.; Maity, A.; Gray, T.G.; Berdis, A.J. “A Metal-containing Nucleoside That Possesses Both Therapeutic and Diagnostic Activity against Cancer” J. Biol. Chem. 2015, 290, 9714-9726. (DOI: 10.1074/jbc.M114.620294)
Maity, A.; Stanek, R.J.; Anderson, B.L.; Zeller, M.; Hunter, A.D.; Moore, C.E.; Rheingold, A.L.; Gray, T.G. “Fluoride Complexes of Cyclometalated Iridium(III)” Organometallics 2015, 34, 109-120. (DOI: 10.1021/om5009555)
Maity, A.; Sulicz, A.N.; Deligonul, N.; Zeller, M.; Hunter, A.D.; Gray, T.G. “Suzuki–Miyaura coupling of arylboronic acids to gold(III)” Chemical Science 2015, 6, 981-986. (DOI: 10.1039/C4SC02148G)
Browne, A.R.; Deligonul, N.; Anderson, B.L.; Rheingold, A.L.; Gray, T.G. “Geminally Diaurated Aryls Bridged by Semirigid Phosphine Pillars: Syntheses and Electronic Structure” Chemistry – A European Journal 2015, 20, 17552-17564. (DOI: 10.1002/chem.201403444)
Deligonul, N.; Browne, A.R.; Golen, J.A.; Rheingold, A.L.; Gray, T.G. “Cyclometalated Iridium(III) Complexes of Azadipyrromethene Chromophores” Organometallics 2014, 33, 637-643. (DOI: 10.1021/om4007032)
Deligonul, N.; Gray, T.G. “Azadipyrromethene Complexes of d8 Metal Centers: Rhodium(I), Iridium(I), Palladium(II), and Platinum(II)” Inorganic Chemistry 2013, 52, 13048-13057. (DOI: 10.1021/ic4017239)
Wyss, C.M.; Tate, B.K.; Basca, J.; Gray, T.G.; Sadighi, J.P. “Bonding and Reactivity of a μ-Hydrido Dicopper Cation” Angew. Chem. Int. Ed. 2013, 52, 12920–12923. (DOI: 10.1002/anie.201306736)
Maity, A.; Choi, J.-S.; Teets, T.S.; Deligonul, N.; Berdis, A.J.; Gray, T.G. “Cyclometalated Iridium(III) Complexes with Deoxyribose Substituents” Chemistry — A European Journal 2013, 19, 15924-15932.(DOI: 10.1002/chem.201301776)
Robilotto, T.J.; Deligonul, N.; Updegraff, J.B., III; Gray, T.G. “Azido, Triazolyl, and Alkynyl Complexes of Gold(I): Syntheses, Structures, and Ligand Effects” Inorganic Chemistry 2013, 52, 9659-9668.(DOI: 10.1021/ic4014569)
Heckler, J.E.; Deligonul, N.; Rheingold, A.L.; Gray, T.G. “Gold(I) triazolyls: organometallic synthesis in air and aqueous media” Chemical Communications 2013, 49, 5990-5992. (DOI: 10.1039/C3CC43016B)
Maity, A.; Anderson, B. L.; Deligonul, N; Gray, T. G. “Room-temperature synthesis of cyclometalated iridium(III) complexes: kinetic isomers and reactive functionalities” Chemical Science 2013, 4, 1175-1181. (DOI: 10.1039/C2SC21831C)
Robilotto, T. J.; Basca, J.; Gray, T. G.; Sadighi, J. P. “Synthesis of a Trigold Monocation: An Isolobal Analogue of [H3]+” Angewandte Chemie, International Edition 2012, 51, 12077-12080. (DOI: 10.1002/anie.201206712); Angewandte Chemie 2012, 124, 12243-12246. (DOI: 10.1002/ange.201206712)
Lenker, H. K.; Gray, T. G.; Stockland, R. A., Jr. “Rapid Synthesis of Arylgold Compounds Using Dielectric Heating” Dalton Transactions 2012, 41, 13274-13276. (DOI: 10.1039/C2DT32129G)
Vogt, R. A.; Gray, T. G.; Crespo-Hernández, C. E. “Subpicosecond Intersystem Crossing in Mono- and Di(organophosphine)gold(I) Naphthalene Derivatives in Solution” Journal of the American Chemical Society 2012, 136, 14808-14817. (DOI: 10.1021/ja303592q)
Partyka, D. V.; Zeller, M.; Hunter, A. D.; Gray, T. G. “Arylgold(I) Complexes from Base-Assisted Transmetalation: Structures, NMR Properties, and Density-Functional Theory Calculations” Inorganic Chemistry 2012, 51, 8394-8401. (DOI: 10.1021/ic3009464)
Gao, L.; Deligonul, N.; Gray, T. G. “Gold(I) Complexes of Brominated Azadipyrromethene Ligands” Inorganic Chemistry 2012, 51, 7682–7688. (DOI: 10.1021/ic300709n)
Heckler, J. E.; Zeller, M.; Hunter, A. D.; Gray, T. G. “Geminally Diaurated Gold(I) Aryls from Boronic Acids” Angewandte Chemie, International Edition 2012, 51, 5924-5928. (DOI: 10.1002/anie.201201744)
Gao, L.; Niedzwiecki, D. S.; Deligonul, N.; Zeller, M.; Hunter, A. D.; Gray, T. G. “Gold(I) Styrylbenzene, Distyrylbenzene, and Distyrylnaphthalene Complexes: High Emission Quantum Yields at Room Temperature” Chemistry–A European Journal 2012, 18, 6316-6327. (DOI: 10.1002/chem.201102502)
Craig, S.; Gao, L.; Lee, I.; Gray, T.; Berdis, A. J. “Gold-Containing Indoles as Anticancer Agents That Potentiate the Cytotoxic Effects of Ionizing Radiation” Journal of Medicinal Chemistry 2012, 55, 2437-2451. (DOI: 10.1021/jm2005942)
Partyka, D. V.; Teets, T. S.; Zeller, M.; Updegraff, J. B., III; Hunter, A. D.; Gray, T. G. “Constrained Digold(I) Diaryls: Syntheses, Crystal Structures, and Photophysics” Chemistry–A European Journal 2012, 18, 2100-2112. (DOI: 10.1002/chem.201101891)
Peay, M. A.; Heckler, J. E.; Deligonul, N.; Gray, T. G. “Red-Shifts upon Metal Binding: A Di-Gold(I)-Substituted Bithiophene” Organometallics 2011, 30, 5071–5074. (DOI: 10.1021/om2003267)
Robilotto, T. J.; Alt, D. S.; von Recum, H. A.; Gray, T. G. “Cytotoxic gold(I)-bearing dendrimers from alkyne precursors” Dalton Transactions 2011, 40, 8035-8085. (DOI: 10.1039/C1DT10578G)
Gao, L.; Peay, M. A.; Gray, T. G. “Encapsulation of Phosphine-Terminated Rhenium(III) Chalcogenide Clusters in Silica Nanoparticle” Chemistry of Materials 2010, 22, 6240-6245. (DOI: .1021/cm101609p)
Partyka, D. V.; Updegraff, J. B., III; Zeller, M.; Hunter, A. D.; Gray, T. G. “Gold(I) halide complexes of bis(diphenylphosphine)diphenyl ether ligands: a balance of ligand strain and non-covalent interactions” Dalton Transactions 2010, 39, 5388-5397. (DOI: 10.1039/b920717a)
Vogt, R. A.; Peay, M. A.; Gray, T. G.; Crespo-Hernández, C. E. “Excited-State Dynamics of (Organophosphine)gold(I) Pyrenyl Isomers” Journal of Physical Chemistry Letters 2010, 1, 1205-1211. (DOI: 10.1021/jz100052m)
Partyka, D. V.; Gao, L.; Teets, T. S.; Updegraff, J. B., III; Deligonul, N.; Gray, T. G. “Copper-Catalyzed Huisgen [3+2] Cycloaddition of Gold(I) Alkynyls with Benzyl Azide. Syntheses, Structures, and Optical Properties” Organometallics 2009, 28, 6171–6182. (DOI: 10.1021/om9005774)
Partyka, D. V.; Deligonul, N.; Washington, M. P.; Gray, T. G. “fac-Tricarbonyl Rhenium(I) Azadipyrromethene Complexes” Organometallics 2009, 28, 5837-5840. (DOI: 10.1021/om900552e)
Gao, L.; Peay, M. A.; Partyka, D. V.; Updegraff, J. B., III; Teets, T. S.; Esswein, A. J.; Zeller, M.; Hunter, A. D.; Gray, T. G. “Mono- and Di-Gold(I) Naphthalenes and Pyrenes: Syntheses, Crystal Structures, and Photophysics” Organometallics 2009, 28, 5669-5681. (DOI: 10.1021/om9005214)
Teets, T. S.; Updegraff, J. B., III; Esswein, A. J.; Gray, T. G. “Three-Coordinate, Phosphine-Ligated Azadipyrromethene Complexes of Univalent Group 11 Metals” Inorganic Chemistry 2009, 48, 8134-8144.(DOI: 10.1021/ic900208a)
Partyka, D. V.; Washington, M. P.; Gray, T. G.; Updegraff, J. B., III; Turner, J. F., II; Protasiewicz, J. P. “Unusual Phosphorus-Phosphorus Double Bond Contraction upon Mono- and Di-auration of a Diphosphene” Journal of the American Chemical Society 2009, 131, 10041-10048. (DOI: 10.1021/ja900813v)
Gao, L.; Partyka, D. V.; Updegraff, J. B., III; Deligonul, N.; Gray, T. G. “Synthesis, Structures, and Excited-State Geometries of Alkynylgold(I) Complexes” European Journal of Inorganic Chemistry 2009, 2711-2719. (DOI: 10.1002/ejic.200900307)
Partyka, D. V.; Updegraff, J. B., III; Zeller, M.; Hunter, A. D.; Gray, T. G. “Probing the Steric Limits of Carbon-Gold Bond Formation: (Dialkylbiarylphosphine)gold(I) Aryls” Organometallics 2009, 28, 1666-1674. (DOI: 10.1021/om800746u)
Gray, T. G. “Divergent Electronic Structures of Isoelectronic Metalloclusters: Tungsten(II) Halides and Rhenium(III) Chalcogenide Halides” Chemistry: A European Journal 2009, 15, 2581-2593. (DOI: 10.1002/chem.200800152)
Partyka, D. V.; Robilotto, T. J.; Updegraff, J. B., III; Zeller, M.; Hunter, A. D.; Gray, T. G. “Facile Synthesis of (Phosphine)- and (N-heterocyclic Carbene)Gold(I) and Silver(I) Azide Complexes” Organometallics 2009, 28, 795-801. (DOI: 10.1021/om800536f)
Partyka, D. V.; Robilotto, T. J.; Zeller, M.; Hunter, A. D.; Gray, T. G. “A porphyrin complex of Gold(I): (Phosphine)gold(I) azides as cation precursors” Proceedings of the National Academy of Sciences 2008,105 , 14293-14297. (DOI: 10.1073/pnas.0806520105)
Teets, T. S.; Partyka, D. V.; Updegraff, J. B., III; Gray, T. G. “Homoleptic, Four-Coordinate Azadipyrromethene Complexes of d10 Zinc and Mercury” Inorganic Chemistry 2008, 47, 2338-2346. (DOI: 10.1021/ic701190g)
Partyka, D. V.; Robilotto, T. J.; Zeller, M.; Hunter, A. D.; Gray, T. G. “Dialkylbiarylphosphine Complexes of Gold(I) Halides. Gold-Aryl π-Interactions in the Solid State” Organometallics 2008, 27, 28-32.(DOI: 10.1021/om700517q)
Gray, T. G. “Gilded Organometallics” Comments on Inorganic Chemistry 2007, 28, 181-212. (DOI: 10.1080/02603590701849025)
Teets, T. S.; Partyka, D. V.; Esswein, A. J.; Updegraff, J. B., III; Zeller, M.; Hunter, A. D.; Gray, T. G. “Luminescent, Three-Coordinate Azadipyrromethene Complexes of d10 Copper, Silver, and Gold” Inorganic Chemistry 2007, 46, 6218-6220. (DOI: 10.1021/ic700776t)
Partyka, D. V.; Esswein, A. J.; Zeller, M.; Hunter, A. D.; Gray, T. G. “Gold(I) Pyrenyls: Excited-State Consequences of Carbon-Gold Bond Formation” Organometallics 2007, 26, 3279-3282. (DOI: 10.1021/om700346v)
Partyka, D. V.; Updegraff, J. B., III; Zeller, M.; Hunter, A. D.; Gray, T. G. “Carbon-Gold Bond Formation through [3+2] Cycloaddition Reactions of Gold(I) Azides and Terminal Alkynes” Organometallics 2007, 26, 183-186. (DOI: 10.1021/om0607200)
Peay, M.; Updegraff, J. B., III; Gray, T. G. “Bis(tetraphenylphosphonium) octa-μ3-chloro-hexakis(trifluoromethanesulfonato)- octahedro-hexamolybdate dichloromethane/diethyl ether solvate” Acta Crystallographica Section E 2006, 62, 2895-2897. (DOI: 10.1107/S1600536806040517)
Partyka, D. V.; Zeller, M.; Hunter, A. D.; Gray, T. G. “Relativistic Functional Groups: Aryl Carbon-Gold Bond Formation by Selective Transmetalation of Boronic Acids” Angewandte Chemie International Edition 2006, 45, 8188-8191. (DOI: 10.1002/anie.200603350)